Bis[4-amino-N-(pyrimidin-2-yl)benzenesulfonamidato](1,10-phenanthroline)nickel(II)
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چکیده
In the mononuclear title compound, [Ni(C(10)H(9)N(4)O(2)S)(2)(C(12)H(8)N(2))], the Ni(II) atom has a distorted octa-hedral coordination geometry comprising four N atoms from two 4-amino-N-(pyrimidin-2-yl)benzene-sulfonamidate ligands and two N atoms from a 1,10-phenanthroline ligand. In the crystal, mol-ecules are connected into a three-dimensional supra-molecular network via N-H⋯O hydrogen bonds and weak C-H⋯O and C-H⋯N contacts.
منابع مشابه
Tris(N-{bis[methyl(phenyl)amino]phosphoryl}benzenesulfonamidato-κ2 O,O′)(1,10-phenanthroline-κ2 N,N′)lanthanum(III)
The asymmetric unit of [La(C20H21N3O3PS)3(C12H8N2)] is created by one LaIII ion, three deprotonated N-{bis-[meth-yl(phen-yl)amino]-phosphor-yl}benzene-sulfonamidate (L-) ligands and one 1,10-phenanthroline (Phen) mol-ecule. Each LaIII ion is eight-coordinated (6O+2N) by three phosphoryl O atoms, three sulfonyl O atoms of three L- ligands and two N atoms of the chelating Phen ligand, leading to ...
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The title compound, [Mn(C(10)H(9)N(4)O(2)S)(2)(C(10)H(8)N(2))], contains a distorted octa-hedral [Mn(sdz)(2)(bpy)] (sdz is the sulfadiazine anion and bpy is 2,2'-bipyridine) complex mol-ecule. A three-dimensional network is generated by N-H⋯N, N-H⋯O and C-H⋯O hydrogen bonds from the sulfadiazine ligands.
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The title complex, [Co(C(10)H(9)N(4)O(2)S)(2)(C(3)H(7)NO)(2)], lies across an inversion center. The Co(II) atom is coordinated in a slightly distorted octa-hedral geometry by four N atoms from two bidentate 4-amino-N-(pyrimidin-2-yl)benzene-sulfonamidate (sulfadiazine) anions and two O atoms from two dimethyl-formamide (DMF) ligands. The dihedral angle between the benzene and pyrimidine rings i...
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The title complex, [Ni2(C9H4O6)2(C13H8N4)2(H2O)4]·2H2O, bis-(μ-5-carb-oxy-benzene-1,3-di-carboxyl-ato-κ(2) O (1):O (1'))bis-[di-aqua(1H-imidazo[4,5-f][1,10]phenanthroline-κ(2) N (7),N (8))nickel(II)] di-hydrate, was obtained under solvothermal conditions by the reaction of benzene-1,3,5-tricarboxylic acid (H3BTC) with Ni(NO3)2 in the presence of 1H-imidazo[4,5-f][1,10]phenanthroline (IP). The c...
متن کاملtrans-Bis[4-amino-N-(pyrimidin-2-yl)benzenesulfonamidato]dipyridinenickel(II) hemihydrate
The asymmetric unit of the title compound, [Ni(C(10)H(9)N(4)O(2)S)(2)(C(5)H(5)N)(2)]·0.5H(2)O, contains the distorted octa-hedral trans-[Ni(sdz)(2)(py)(2)] (sdz is the sulfadiazine anion and py is pyridine) complex mol-ecule and half of a water mol-ecule. A three-dimensional network is generated by N-H⋯O and O-H⋯O hydrogen bonds and C-H⋯O inter-actions between the complex and the water mol-ecules.
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